Visible-light harvesting iridium complexes as singlet oxygen sensitizers for photooxidation of 1,5-dihydroxynaphthalene.
نویسندگان
چکیده
Visible-light harvesting cyclometalated Ir(III) complexes were used as (1)O(2) sensitizers for the photooxidation of 1,5-dihydroxynaphthalene (DHN) and substantially improved photooxidation capability was observed compared to the conventional Ir(III) complex sensitizers that show no visible light-harvesting capabilities.
منابع مشابه
Photooxidation of 1,5-dihydroxynaphthalene with iridium complexes as singlet oxygen sensitizers.
Photooxidation reactions of 1,5-dihydroxynaphthalene (DHN) have been carried out in the presence of cyclometalated neutral and cationic iridium (Ir) complexes 1-6 as singlet oxygen ((1)O(2)) sensitizers in order to investigate the (1)O(2) generation quantum yield and photosensitizing durability of the complexes. The reactions allowed a successful kinetic study to provide the pseudo-first-order ...
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ورودعنوان ژورنال:
- Chemical communications
دوره 48 35 شماره
صفحات -
تاریخ انتشار 2012